کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325348 | 977379 | 2011 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis and reactivity of stable trisyl(aminomethylphenyl)silylenoid
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
A highly thermally stable silylenoid, trisyl(aminomethylphenyl)silylenoid (2) was synthesized from the reaction of dimethylaminomethylphenyllithium with a bromosilylenoid, 1. Silylenoid 2 reacted with electrophiles to give the corresponding products, but did not react with alkyllithiums as a nucleophile.
Figure optionsDownload as PowerPoint slideHighlights
► A highly thermally stable trisyl(aminomethylphenyl)silylenoid was synthesized.
► Our result provides a new synthetic strategy for congested organosilicon compounds.
► This is the first example of a stable silylenoid having intramolecular donor atom.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 13, 1 July 2011, Pages 2665–2668
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 13, 1 July 2011, Pages 2665–2668
نویسندگان
Hyeon Mo Cho, Young Mook Lim, Byung Wook Lee, Sung Jin Park, Myong Euy Lee,