کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325429 | 977382 | 2009 | 4 صفحه PDF | دانلود رایگان |
A series of silver complexes generated in situ from AgOSO2CF3 (AgOTf) and a range of bidentate ligands were investigated as catalysts for the intramolecular hydroamination of 4-pentyn-1-amine. A variety of P- and N-donor ligands were tested including the novel pyrazole-phosphine ligand 1-(2-(diphenylphosphino)phenyl)pyrazole. The best catalyst was formed from equimolar amounts of the P,N-donor ligand 1-(2-(diphenylphosphino)ethyl)pyrazole and AgOTf, which achieved a turnover rate of 129 h−1 for the cyclisation of 4-pentyn-1-amine.
Silver complexes generated in situ from AgOTf and a series of bidentate P- and N-donor ligands, including the novel pyrazole-phosphine ligand 1-(2-(diphenylphosphino)phenyl)pyrazole, were investigated as catalysts for the intramolecular hydroamination of 4-pentyn-1-amine. The best catalyst (turnover rate = 129 h−1) was formed from equimolar ammounts of 1-(2-(diphenylphosphino)ethyl)pyrazole and AgOTf.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 2, 15 January 2009, Pages 309–312