کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325715 | 977396 | 2006 | 6 صفحه PDF | دانلود رایگان |
A new dinitrogen rhenium(I) complex with a picolinate ligand has been prepared and fully characterized, providing the first example of a genuine NN complex bearing a carboxylate or a N,O-coligand. The Lever electrochemical EL ligand parameter was estimated for the first time for the picolinate ligand and shows that its carboxylate arm has a net electron-donor character similar to that of chloride, thus stabilizing the trans Re–N2 bond.
A dinitrogen Re(I) complex with a picolinate ligand has been prepared, providing the first example of a genuine NN complex comprising a carboxylate or a N,O-coligand, the carboxylate arm of picolinate having a net electron-donor character similar to that of chloride, stabilizing the trans Re–N2 bond.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 19, 15 September 2006, Pages 4153–4158