کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325781 | 977401 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The first metallacarborane triple-decker complexes with a bridging borole ligand
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
The (borole)iodide complex [(η5-C4H4BPh)RhI]4 reacts with the carborane anion [Carb′]− (Carb′ = 9-SMe2-7,8-C2B9H10) giving (Carb′)Rh(η5-C4H4BPh) (2). Reactions of 2 with dicationic fragments [LM]2+ afford the μ-borole triple-decker complexes [(Carb′)Rh(μ-η5:η5-C4H4BPh)ML]2+ [LM = Cp∗Ir (4), (Carb′)Rh (7)] or the arene-type complexes [(Carb′)Rh(μ-η5:η6-C4H4BPh)ML]2+ [LM = Cp∗Rh (3), (Carb′)Ir (8)]. The structure of 4(BF4)2 was determined by X-ray diffraction.
The first metallacarborane triple-decker complexes with a bridging borole ligand were prepared by stacking reactions of (borole)rhodacarborane (Carb′)Rh(η5-C4H4BPh) (Carb′ = 9-SMe2-7,8-C2B9H10) with [Cp∗Ir]2+ or [(Carb′)Rh]2+ fragments.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 17, 15 August 2006, Pages 3646–3651
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 17, 15 August 2006, Pages 3646–3651
نویسندگان
Dmitry A. Loginov, Dmitry V. Muratov, Zoya A. Starikova, Pavel V. Petrovskii, Alexander R. Kudinov,