کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1325799 | 1499943 | 2010 | 7 صفحه PDF | دانلود رایگان |
New methylnaphthalene-linked imidazolium salts 1 were synthesized through the reaction of 1,8-dibromomethylnaphthalene and N-alkylimidazole. On treatment of imidazolium salt 1 with silver oxide followed by [Cp∗MCl2]2 (M = Ir, Rh), binuclear iridium and rhodium complexes 2 were formed. Reaction of these complexes 2 with AgPF6 afforded Cl-bridged cationic binuclear iridium and rhodium complexes 3. X-ray crystallographic analysis of 3 revealed that the two imidazole rings of the carbene ligand are in a parallel geometry. The cationic binuclear iridium complexes 3-Ir could be applied to the intramolecular hydroamination reaction of 2-ethynylaniline to give the corresponding indole compound.
An binuclear iridium(III) and rhodium (III) complex bearing a methylnaphthalene-linked N-heterocyclic carbene was prepared by the reaction of [Cp∗MCl2]2 (M = Ir, Rh) with silver NHC complex. On treatment of the binuclear neutral complexes with AgPF6, the Cl-bridged cationic iridium and rhodium complexes were formed. The cationic iridium complex could be applied to the intramolecular hydroamination of 2-ethynylaniline to give the corresponding indole compound.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 695, Issues 12–13, 1 June 2010, Pages 1675–1681