کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325828 | 977404 | 2008 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: The reactivity of a nucleophilic nickel acylate complex The reactivity of a nucleophilic nickel acylate complex](/preview/png/1325828.png)
The reactivity of a nucleophilic nickel acylate complex with a tungsten carbene complex, Fe(CO)5, Cr(CO)6, PPh3, and CO was investigated. With the tungsten carbene complex, a methyl transfer occurred. With the metal carbonyl complexes, the acylate group on the nickel and a carbonyl on the iron or chromium traded places. With the PPh3 and CO, the acylate anion was replaced by the phosphine or CO ligand.
The reactivity of a nucleophilic nickel acylate complex with a tungsten carbene complex, Fe(CO)5, Cr(CO)6, PPh3, and CO was investigated. With the tungsten carbene complex, a methyl transfer occurred. With the metal carbonyl complexes, the acylate group on the nickel and a carbonyl on the iron or chromium traded places. With the PPh3 and CO, the acylate anion was replaced by the phosphine or CO ligand.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 11, 15 May 2008, Pages 2061–2064