کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325894 | 977409 | 2008 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reaction of 3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocene with [Re2(CO)8(CH3CN)2]: Novel coordination modes of the 1,1′-diphosphaferrocene ligand
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Reaction of 3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocene with [Re2(CO)8(CH3CN)2]: Novel coordination modes of the 1,1′-diphosphaferrocene ligand Reaction of 3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocene with [Re2(CO)8(CH3CN)2]: Novel coordination modes of the 1,1′-diphosphaferrocene ligand](/preview/png/1325894.png)
چکیده انگلیسی
Reaction of 3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocene (1) with [Re2(CO)8(CH3CN)2] afforded two trimetallic complexes in which the heterometallocene is ligated across the Re–Re bond. The structure of the complex having 1 bridging the Re2(CO)8 moiety through two P atoms was determined by X-ray diffraction and compared with those of analogous complexes with organic bridging bis-phosphines. The second complex obtained in this reaction presumably contains 1 acting as a (P,Fe) bridging ligand.
Reaction of 3,3′,4,4′-tetramethyl-1,1′-diphosphaferrocene with [Re2(CO)8(CH3CN)2] afforded two trimetallic complexes in which the heterometallocene is ligated across the Re–Re bond through P,P and P,Fe atoms.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 7, 1 April 2008, Pages 1166–1170
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 7, 1 April 2008, Pages 1166–1170
نویسندگان
Arkadiusz Kłys, Agnieszka Rybarczyk-Pirek, Janusz Zakrzewski,