کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1325903 | 977409 | 2008 | 9 صفحه PDF | دانلود رایگان |

A series of N-alkyl-substituted cyclopalladated ferrocenylimines were used in palladium-catalyzed Suzuki–Miyaura cross-coupling reactions of aryl halides in room temperature and CH3OH/H2O media under aerobic conditions. As for the catalysts, the length of N-alkyl chains has no significant effect on the catalytic activity. Using 0.01 mol% of dimer 3a in the presence of K2CO3 as base offered excellent yields in the reaction of activated and non-activated aryl bromides with phenylboronic acid.
A series of N-alkyl-substituted cyclopalladated ferrocenylimines were used in palladium-catalyzed Suzuki–Miyaura cross-coupling reactions of aryl halides in room temperature and CH3OH/H2O media under aerobic conditions. Good to excellent yields were obtained with lower catalyst loading and short reaction time.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 7, 1 April 2008, Pages 1243–1251