کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1325940 977411 2006 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of pyridine- and thiophene-based platinacyclynes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of pyridine- and thiophene-based platinacyclynes
چکیده انگلیسی

Seven heterocyclic macrocycles, including the first platinacycles with pyridine and thiophene rings incorporated into the cyclyne system, are reported. Pt-acetylide cyclynes were assembled via tin transmetallation or amine-mediated oxidative addition with stoichiometric PtCl2(PEt3)2 and CuI. The organometallic cyclynes exhibited enhanced electronic properties compared to previously described platinabenzocyclynes.

Seven heterocyclic macrocycles, including the first platinacycles with pyridine and thiophene rings incorporated into the cyclyne system, are reported. Pt-acetylide cyclynes were assembled via tin transmetallation or amine-mediated oxidative addition with stoichiometric PtCl2(PEt3)2 and CuI.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 3, 15 January 2006, Pages 413–421
نویسندگان
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