Synthesis and structural characterization of new piano-stool ruthenium(II) complexes bearing 1-butylimidazole heteroaromatic ligand

New cationic ruthenium(II) complexes with the formula [Ru(η5-C5H5)(LL)(1-BuIm)] [Z], with (LL) = 2PPh3 or DPPE, and Z = CF3SO3−, PF6−, BPh4−, have been synthesized and fully characterized. Spectroscopic and electrochemical studies revealed that the electronic properties of the coordinated 1-butylimidazole were clearly influenced by the nature of the phosphane coligands (LL) and also by the different counter ions. The solid state structures of the six complexes determined by X-ray crystallographic studies, confirmed the expected distorted three-legged piano stool structure. However the geometry of the 1-butylimidazole ligand was found considerably different in all six compounds, being governed by the stereochemistry of the mono and bidentate coligands (PPh3 or DPPE).

Six new ruthenium(II) cationic complexes containing 1-butylimidazole ligand. Study of the influence of the coligands and counter ions on the chemical and solid state structural features.Figure optionsDownload as PowerPoint slideHighlights
► Unexpected redox properties of butylimidazole due interaction with the counter ion.
► Strong effect of coligands and counter ions in butylimidazole conformation.
► Six single crystal structures determined by X-ray diffraction studies.