کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326038 | 977415 | 2008 | 13 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Synthesis, spectroscopic and electronic characterizations of two half sandwich ruthenium(II) complexes with 2-(2′-hydroxyphenyl)-benzoxazole and 4-picolinic acid ligands Synthesis, spectroscopic and electronic characterizations of two half sandwich ruthenium(II) complexes with 2-(2′-hydroxyphenyl)-benzoxazole and 4-picolinic acid ligands](/preview/png/1326038.png)
The [(C6H6)RuCl(HPB)] and [(C6H6)RuCl2(C5H4NCOOH)] complexes have been prepared and studied by IR, UV–Vis spectroscopy and X-ray crystallography. The complexes was prepared in reaction of [(C6H6)RuCl2]2 with 2-(2′-hydroxyphenyl)-benzoxazole or 4-picolinic acid in methanol. The electronic spectra of the obtained compounds have been calculated using the TDDFT method. The luminescence property of the half sandwich complex [(C6H6)RuCl(HPB)] was studied by the DFT method and the mechanism was suggested.
The [(C6H6)RuCl(HPB)] and [(C6H6)RuCl2(C5H4NCOOH)] complexes have been prepared and studied by IR, UV–Vis spectroscopy and X-ray crystallography. The complexes was prepared in reaction of [(C6H6)RuCl2]2 with 2-(2′-hydroxyphenyl)-benzoxazole or 4-picolinic acid in methanol. The electronic spectra of the obtained compounds have been calculated using the TDDFT method. The luminescence property of the half sandwich complex [(C6H6)RuCl(HPB)] was studied by the DFT method and the mechanism was suggested.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 6, 15 March 2008, Pages 1096–1108