کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326052 | 1499953 | 2005 | 9 صفحه PDF | دانلود رایگان |
The coordination chemistry of technetium and rhenium with N-heterocyclic carbenes of the dimethylimidazol-2-ylidene and 1,2,4-triazol-5-ylidene types is reviewed. Compounds containing the metals in the oxidation states “+7”, “+5” and “+1” are introduced. General trends and differences in the chemical behaviour of the complexes, particularly between the different metal cores (oxo, nitrido, imido) of Tc(V) and Re(V) compounds, are discussed. The influence of electronic and steric factors for the stabilisation of the metal complexes is explored.
The coordination chemistry of technetium and rhenium with N-heterocyclic carbenes of the dimethylimidazol-2-ylidene and 1,2,4-triazol-5-ylidene types is reviewed. General trends and differences in the chemical behaviour of the complexes, particularly between the different metal cores (oxo, nitrido, imido) of Tc(V) and Re(V) compounds, are discussed.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 690, Issues 24–25, 1 December 2005, Pages 5421–5429