کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326065 | 1499953 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A stable (amino)(phosphino)carbene as bidentate ligand for palladium and nickel complexes: Synthesis, structure, and catalytic activity
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Two original complexes featuring an (amino)(phosphino)carbene η2-bonded to the metal have been obtained in 60% and 80% yields, by addition of the corresponding stable carbene to PdCl2(cod) and NiCl2(PPh3)2, respectively. Both complexes have been fully characterized including X-ray diffraction studies. The catalytic activity of the palladium complex has been evaluated for aryl amination reactions.
Two original Pd and Ni complexes featuring an (amino)(phosphino)carbene η2-bonded to the metal have been prepared and the catalytic activity of the palladium complex was evaluated for aryl-amination reactions.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issues 24–25, 1 December 2005, Pages 5541–5545
Journal: Journal of Organometallic Chemistry - Volume 690, Issues 24–25, 1 December 2005, Pages 5541–5545
نویسندگان
Emmanuelle Teuma, Céline Lyon-Saunier, Heinz Gornitzka, Gérard Mignani, Antoine Baceiredo, Guy Bertrand,