کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326066 | 1499953 | 2005 | 6 صفحه PDF | دانلود رایگان |
Bis(iodozincio)methane, which has been shown to be an efficient reagent for organic synthesis, is obtained as THF solution. The structural information about the reagent as THF solution was corrected by small angle neutron scattering and by anomalous X-ray scattering. Those scattering experiments implied that the prepared bis(iodozincio)methane exists without forming any oligomer or aggregate. A coordination of tetrahydrothiophene to bis(iodozincio)methane enhances the nucleophilicity of the reagent and stabilizes its monomeric structure in the solution.
The structural information about bis(iodozincio)methane as THF solution was corrected by small angle neutron scattering and by anomalous X-ray scattering. Those scattering experiments implied that the prepared bis(iodozincio)methane exists without forming any oligomer or aggregate.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 690, Issues 24–25, 1 December 2005, Pages 5546–5551