کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1326089 1499953 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Novel rhodium complexes with ferrocene-based N-heterocylic carbenes: Synthesis, structure and catalysis
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Novel rhodium complexes with ferrocene-based N-heterocylic carbenes: Synthesis, structure and catalysis
چکیده انگلیسی

The synthesis of a chiral N-heterocyclic carbene with an oxazolinyl ferrocenyl substituent is reported. The X-ray crystal structure of a rhodium complex reveals the chelating properties of the ligand, and catalysis studies demonstrate the capability of the rhodium complexes to catalyze hydrosilylations of ketones.

The synthesis of a chiral N-heterocyclic carbene (NHC) with an oxazolinyl ferrocenyl substituent is reported. Catalysis studies demonstrate the capability of the rhodium complexes to catalyze hydrosilylations of ketones, and an X-ray crystal structure reveals the chelating properties of the ligand.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 690, Issues 24–25, 1 December 2005, Pages 5747–5752
نویسندگان
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