کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1326144 977417 2010 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A novel conjugated [2]rotaxane with an Ru-containing axle constructed from a carboxy-functionalized bis-terpyridyl ruthenium complex and β-cyclodextrin: Synthesis, characterization, and properties
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A novel conjugated [2]rotaxane with an Ru-containing axle constructed from a carboxy-functionalized bis-terpyridyl ruthenium complex and β-cyclodextrin: Synthesis, characterization, and properties
چکیده انگلیسی

A novel Ru-containing conjugated [2]rotaxane, which utilizes a carboxy-functionalized bis-terpyridyl ruthenium complex as an end group, has been prepared by Suzuki coupling in the presence of β-cyclodextrin (β-CD). The structure has been characterized by NMR spectroscopy and ESI mass spectrometry. Its photophysical properties have shown that insulation by the cyclodextrin reduces the fluorescence intensity compared to that of the free dumbbell.

A novel Ru-containing conjugated [2]rotaxane, which utilizes a carboxy-functionalized bis-terpyridyl ruthenium complex as an end group, has been prepared by Suzuki coupling in the presence of β-CD, and its photophysical properties have shown that insulation by the cyclodextrin reduces the fluorescence intensity compared to the free dumbbell.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 3, 1 February 2010, Pages 323–326
نویسندگان
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