Epoxidation in ionic liquids: A comparison of rhenium(VII) and molybdenum(VI) catalysts

Complexes of the type (dimethyl-bpy)MoO2Cl2 and Schiff/Lewis-base complexes of methyltrioxorhenium (MTO), being efficient homogeneous catalysts for the epoxidation of olefins, have been examined with respect to their catalytic performance at 55 and 25 °C in systems employing room temperature ionic liquids (RTILs) of composition [BMIM]NTf2, [BMIM]PF6, [BMIM]BF4 and [C8MIM]PF6 as solvents. The performance in the cyclooctene epoxidation was observed to be strongly dependent on the water content of the system and the catalyst solubility in the RTIL. MTO based systems prove to be superior with respect to lower energy consumption, higher stability and higher product yields compared to the investigated Mo(VI) system under the conditions applied.

Lewis base complexes of MoO2Cl2 and methyltrioxorhenium (MTO) and Schiff-base complexes of MTO have been examined for the epoxidation of cis-cyclooctene in selected room temperature ionic liquids. MTO turns out to be a much more active and stable catalyst than the water sensitive Mo(VI) compound.Figure optionsDownload as PowerPoint slide