کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326307 | 1499931 | 2012 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Highly porous chitosan microspheres supported palladium catalyst for coupling reactions in organic and aqueous solutions Highly porous chitosan microspheres supported palladium catalyst for coupling reactions in organic and aqueous solutions](/preview/png/1326307.png)
Porous chitosan microspheres (PCMS) were prepared from crosslinking chitosan/polyethylene glycol (PEG) interpenetrating microspheres through selective dissolution of the water-soluble PEG component for the immobilization of palladium catalyst. The resultant Pd/PCMS supported palladium has been demonstrated as a highly active and easily recyclable heterogeneous catalyst for the Ullmann-type reductive homocoupling of aromatic halides and the Heck cross-coupling of aromatic halides with acrylates. Most interestingly, the prepared Pd/PCMS heterogeneous palladium catalyst can also be employed in the environmentally-benign aqueous solution due to the highly hydrophilic hydroxyl and amino functional groups of chitosan. The large size of the microsphere structure can greatly facilitate separation and recycling of the expensive and toxic palladium catalysts from the reaction mixture and the recovered Pd/PCMS catalyst can preserve the catalytic activity and selectivity for the Heck reaction without any observable degradation over ten recycling times. The high activity and stability of the Pd/PCMS catalyst have been attributed to a combination of the high specific surface area of the porous structure as well as the strong chelation of palladium species with the abundant chitosan surface hydroxyl, amino and carbonyl functional groups.
The porous chitosan microspheres supported palladium has been demonstrated as a highly active and easily recyclable heterogeneous catalyst for the Ullmann-type reductive homocoupling of aromatic halides and the Heck cross-coupling of aromatic halides with acrylates .Figure optionsDownload as PowerPoint slideHighlights
► Novel Pd/porous chitosan microspheres heterogeneous catalyst have been prepared.
► It is highly active, selective and recyclable for coupling reactions.
► The preparation of the catalyst is simple and straightforward.
Journal: Journal of Organometallic Chemistry - Volume 704, 1 May 2012, Pages 29–37