کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326373 | 977427 | 2009 | 5 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Palladium catalyzed reductive homocoupling reactions of aromatic halides in dimethyl sulfoxide (DMSO) solution Palladium catalyzed reductive homocoupling reactions of aromatic halides in dimethyl sulfoxide (DMSO) solution](/preview/png/1326373.png)
Biaryls were obtained in good to excellent yields from the palladium catalyzed reductive homocoupling reactions of various aryl iodides and bromides in dimethyl sulfoxide (DMSO) solution without the need for any additional reducing reagents. Pd(dppf)Cl2 is the most effective among the screened palladium catalysts for the homocoupling reactions. Fluorides, carbonates, acetates and hydroxides can be used as bases at promoting the palladium catalyzed reductive homocoupling of aryl halides in DMSO solution. X-ray photoelectron spectroscopic (XPS) analysis shows that the oxidative Pd2+(dppf) species can be reduced into the Pd0(dppf) active species by solvent DMSO molecules to furnish the catalytic cycle, indicating that DMSO plays a dual role as both solvent and reducing reagent. A plausible reaction mechanism has been discussed. Elimination of additional reducing reagents will not only reduce the reaction operation cost, but will also simplify the product separation and purification.
Biaryls were obtained in good to excellent yields from the palladium catalyzed reductive homocoupling reactions of various aryl iodides and bromides in dimethyl sulfoxide (DMSO) solution without the need for any additional reducing reagents.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 18, 15 August 2009, Pages 2912–2916