کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326431 | 977431 | 2005 | 7 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments Chemistry related to cluster-borane analogues of the cyclopentadienide anion and ferrocene: New developments](/preview/png/1326431.png)
A review on cluster-borane analogues of the cyclopentadienide anion (Cp) and ferrocene is presented. Analogues of Cp that have been so far isolated and characterised are the 11-vertex triheteroboranes of general structure [nido-E3B8H8]− (where E = CH or P and their combinations), the molecules of which contain an open pentagonal face. These anions were used as effective ligands for the preparation of “half- and full-sandwich” complexes [CpFeE3B8H8] and [Fe(E3B8H8)2], respectively – analogues of ferrocene. Developments in this area of cluster-borane chemistry that include recent results in the synthesis and Fe-complexation reactions of 11-vertex tricarbaboranes (tricarbollides), phosphadicarbollides, and diphosphacarbollides are the subject of this work.
A review on cluster-borane analogues of the cyclopentadienide anion (Cp) and ferrocene is presented. Triheteroboranes of general structure [nido-E3B8H8]− (where E = CH or P and their combinations) were used as effective ligands for the preparation of “half- and full-sandwich” complexes [CpFeE3B8H8] and [Fe(E3B8H8)2], respectively – analogues of ferrocene.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 11, 1 June 2005, Pages 2694–2700