کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326565 | 977437 | 2009 | 4 صفحه PDF | دانلود رایگان |
The germane intermediate σ-complexes, characterized by high-field resonances in the region from −6 to −8 ppm, have been detected during the 1H NMR spectroscopy monitoring of the photochemical reaction of Et3GeH with Mo(CO)6, [Mo(CO)4(η4-cod)], and [Mo(CO)4(η4-nbd)] in the NMR tube. The activation of the Ge–H bond of germane in photochemical reaction of the norbornadiene (nbd) complex [Mo(CO)4(η4-nbd)] has been applied in the hydrogermylation of norbornadiene, which leads to the formation of triethylgermylnorbornene.
The germane intermediate σ-complexes, characterized by high-field resonances, have been detected during the 1H NMR spectroscopy monitoring of the photochemical reaction of Et3GeH with Mo(CO)6, [Mo(CO)4(η4-cod)], and [Mo(CO)4(η4-nbd)] in the NMR tube. The activation of the Ge–H bond of germane has been applied in the hydrogermylation of norbornadiene.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 13, 1 June 2009, Pages 2110–2113