کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1326567 977437 2009 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis and characterization of three new thermally stable N-heterocyclic germylenes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis and characterization of three new thermally stable N-heterocyclic germylenes
چکیده انگلیسی

Three new stable germylenes, rac-1,3-di-tert-butyl-4,5-dimethyl-1,3-diaza-2-germacyclopentane-2-ylide (1), 1,3-di-tert-butyl-4,4-dimethyl-1,3-diaza-2-germacyclopentane-2-ylide (2), and rac-1,3,4-tri-tert-butyl-1,3-diaza-2-germacyclopentane-2-ylide (3) have been synthesized by the reaction of their corresponding germyl dichlorides with elemental lithium. Full synthetic procedures and characterizations are described.

Three new stable germylenes, rac-1,3-di-tert-butyl-4,5-dimethyl-1,3-diaza-2-germacyclopentane-2-ylide (1), 1,3-di-tert-butyl-4,4-dimethyl-1,3-diaza-2-germacyclopentane-2-ylide (2), and rac-1,3,4-tri-tert-butyl-1,3-diaza-2-germacyclopentane-2-ylide (3) have been synthesized by the reaction of their corresponding dichlorides with elemental lithium. Full synthetic procedures and characterizations are described.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 13, 1 June 2009, Pages 2122–2125
نویسندگان
, , ,