کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326601 | 977438 | 2007 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Direct construction of silicon–silicon bond by using the low-valent titanium reagent Direct construction of silicon–silicon bond by using the low-valent titanium reagent](/preview/png/1326601.png)
The reductive dimerization or polymerization of organochlorosilanes has been achieved by using the low-valent titanium reducing agent other than the alkali metals that are invariable used in the Wurtz-type coupling reaction. Applying this method, the corresponding disilanes or poly(methylvinylsilane) was obtained in good yields. The poly(methylvinylsilane) synthesized by this method is highly pure with a high molecular weight and a narrow molecular weight distribution (Mw/Mn = 1.6, Mn = 16,860).
The reductive dimerization or polymerization of organochlorosilanes has been achieved by using the low-valent titanium reducing agent other than the alkali metals that are invariable used in the Wurtz-type coupling reaction. Applying this method, the corresponding disilanes or poly(methylvinylsilane) was obtained in good yields. The poly(methylvinylsilane) synthesized by this method is highly pure with a high molecular weight and a narrow molecular weight distribution (Mw/Mn = 1.6, Mn = 16,860).Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 16, 15 July 2007, Pages 3559–3562