کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1326608 | 977438 | 2007 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Facile synthesis and X-ray structures of (η5-C5Me5)Ti(OArF)3 (OArF = OC6F5, OCH2C6F5, and OCH2C6F2H3) Facile synthesis and X-ray structures of (η5-C5Me5)Ti(OArF)3 (OArF = OC6F5, OCH2C6F5, and OCH2C6F2H3)](/preview/png/1326608.png)
New half-sandwich titanocene complexes (η5-C5Me5)Ti(OC6F5)3 (1), (η5-C5Me5)Ti(OCH2C6F5)3 (2), and (η5-C5Me5)Ti(OCH2C6F2H3)3 (3) were synthesized via the displacement of methoxide ligands in (η5-C5Me5)Ti(OMe)3 by the corresponding aryloxy or benzyloxy ligands. These compounds have been fully characterized by various spectroscopic methods including X-ray crystallography. Compound 1 has a distorted three-legged piano stool structure. However, complexes 2 and 3 have the chariot-like structure, where chariot means a two-wheeled horse-drawn vehicle. The π electron donation of oxygen atom to Ti center in complexes 1–3 is considerable.
New half-sandwich titanocene complexes (η5-C5Me5)Ti(OC6F5)3 (1), (η5-C5Me5)Ti(OCH2C6F5)3 (2), and(η5-C5Me5)Ti(OCH2C6F2H3)3 (3) were synthesized via methoxide displacement in (η5-C5Me5)Ti(OMe)3 with corresponding aryloxy or benzyloxy ligands. These compounds have been characterized by spectroscopic methods including X-ray crystallography.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 16, 15 July 2007, Pages 3593–3598