کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326631 | 977439 | 2011 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Stereoselective synthesis of a chiral ferrosalen ligand using an aromatization strategy
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A new chiral salen ligand based on two ferrocenyl groups is designed. Unlike known salen ligands, of which chirality originates from central and axial chiral centers, the chirality of this ligand comes from the planar chiral ferrocenyl groups. The ligand is synthesized stereoselectively using a novel aromatization strategy starting from a ferrocene derivative, which was readily prepared using a known chiral auxiliary approach.
Figure optionsDownload as PowerPoint slideHighlights
► Designed a new class of ferrosalen ligand.
► Developed a novel aromatization method for their stereoselective synthesis.
► These ligands will find applications in asymmetric catalysis.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 10, 15 May 2011, Pages 2047–2052
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 10, 15 May 2011, Pages 2047–2052
نویسندگان
Xiang Zhang, Rudy L. Luck, Shiyue Fang,