کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326658 | 977439 | 2011 | 6 صفحه PDF | دانلود رایگان |
FeCl3 was found to be a good catalyst in Se-Se bond cleavage. Further electrophilic additions to methylenecyclopropanes provide a convenient access to diphenylselenylcyclobutanes. Comparing with other Lewis acids, FeCl3 is much cheaper and the reaction conditions are milde and more tolerance to air and moisture.
Iron(III)-catalyzed cleavage of Se–Se bond could generate selenium cations. Further electrophilic additions to methylenecyclopropanes (MCPs) provide a convenient access to synthetic useful diphenylselenylcyclobutanes. Comparing with other Lewis acids, FeCl3 is much cheaper and the reactions are much more tolerant to air and moisture. This FeCl3-catalyzed reaction can be carried out at room temperature and the yields are generally good. All of these advantages facilitate its applications in organic synthesis.Figure optionsDownload as PowerPoint slideHighlights
► In this study, we developed a more advanced synthesis of diphenylselenylcyclobutanes.
► The catalyst FeCl3 is very cheap and its dosage is lower.
► The reaction could be taken under mild conditions.
► Moreover, FeCl3 are more tolerance to air and moisture.
► All of these advantages facilitated the operations.
Journal: Journal of Organometallic Chemistry - Volume 696, Issue 10, 15 May 2011, Pages 2228–2233