کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1326763 977443 2009 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Activation of trimethylsilyl cyanide by potassium phthalimide for facile synthesis of TMS-protected cyanohydrins
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Activation of trimethylsilyl cyanide by potassium phthalimide for facile synthesis of TMS-protected cyanohydrins
چکیده انگلیسی

Potassium phthalimide was found to be a highly effective and easily accessible organocatalyst for the cyanosilylation of various carbonyl compounds under extremely mild conditions. The corresponding cyanohydrin trimethylsilyl ethers were obtained in high to quantitative yields in solvent-free conditions at room temperature using 2.5 mol% catalyst loading.

Potassium phthalimide (PPI) was found to be a highly effective and easily accessible organocatalyst for the cyanosilylation of various carbonyl compounds under extremely mild conditions. The corresponding cyanohydrin trimethylsilyl ethers were obtained in high to quantitative yields in solvent-free conditions at room temperature using 2.5 mol% catalyst loading.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 12, 15 May 2009, Pages 1789–1794
نویسندگان
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