کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1326763 | 977443 | 2009 | 6 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Activation of trimethylsilyl cyanide by potassium phthalimide for facile synthesis of TMS-protected cyanohydrins Activation of trimethylsilyl cyanide by potassium phthalimide for facile synthesis of TMS-protected cyanohydrins](/preview/png/1326763.png)
Potassium phthalimide was found to be a highly effective and easily accessible organocatalyst for the cyanosilylation of various carbonyl compounds under extremely mild conditions. The corresponding cyanohydrin trimethylsilyl ethers were obtained in high to quantitative yields in solvent-free conditions at room temperature using 2.5 mol% catalyst loading.
Potassium phthalimide (PPI) was found to be a highly effective and easily accessible organocatalyst for the cyanosilylation of various carbonyl compounds under extremely mild conditions. The corresponding cyanohydrin trimethylsilyl ethers were obtained in high to quantitative yields in solvent-free conditions at room temperature using 2.5 mol% catalyst loading.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 12, 15 May 2009, Pages 1789–1794