Aliphatic carboncarbon bond activation of ketones by rhodium(II) porphyrin radical

Aliphatic carboncarbon bond activation of both enolizable and non-enolizable ketones occurred successfully with rhodium(II) porphyrin radical to give rhodium(III) porphyrin alkyls. Added Ph3P promoted the yields of products.

Aliphatic carboncarbon bond activation of both enolizable and non-enolizable ketones occurred successfully with rhodium(II) porphyrin radical to give rhodium porphyrin alkyls.Figure optionsDownload as PowerPoint slide