کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1327122 977464 2010 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A molecular-clip-based approach to cofacial zinc–porphyrin complexes
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A molecular-clip-based approach to cofacial zinc–porphyrin complexes
چکیده انگلیسی

We have synthesized molecular-clip-based cofacial zinc–porphyrin complexes. The complexes are shown to be new efficient receptors for the complexation of 1,4-diazabicyclo[2,2,2]octane, acridinium ions, 1,4,5,8-naphthalene tetracarboxylic dianhydride (NTDA) and 1,2,4,5-benzenetetracarboxylic dianhydride (BTDA). Large binding constants (Kasso) in the range of 2.0 × 104–1.1 × 108 M−1 were obtained for the 1:1 complexes of molecular tweezers (3) and rectangle (8) by inserting the hosts between the two porphyrin rings. The values of K and the spectroscopic results suggest that 3 and 8 serve as effective building blocks to capture the hosts. Semi-empirical calculations show that the guests position themselves within the cleft of the bis-porphyrins.

We have synthesized molecular-clip-based cofacial zinc–porphyrin complexes. The complexes are shown to be new efficient receptors for the complexation of 1,4-diazabicyclo[2,2,2]octane, acridinium ions, 1,4,5,8-naphthalene tetracarboxylic dianhydride (NTDA) and 1,2,4,5-benzenetetracarboxylic dianhydride (BTDA).Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 695, Issue 1, 1 January 2010, Pages 111–119
نویسندگان
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