کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327267 | 977471 | 2007 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A diverse structural behaviour of boronated ortho-phthalaldehydes: A crystal structure of 1,3-dihydro-1,3-dihydroxy-4-formylbenzo[c][2,1]oxaborole
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: A diverse structural behaviour of boronated ortho-phthalaldehydes: A crystal structure of 1,3-dihydro-1,3-dihydroxy-4-formylbenzo[c][2,1]oxaborole A diverse structural behaviour of boronated ortho-phthalaldehydes: A crystal structure of 1,3-dihydro-1,3-dihydroxy-4-formylbenzo[c][2,1]oxaborole](/preview/png/1327267.png)
چکیده انگلیسی
Two isomeric boronated ortho-phthalaldehydes 3- and 4-[B(OH)2]-1,2-C6H3(CHO)2 have been prepared and their specific behavior in solution under various conditions has been investigated using NMR spectroscopy. The former compound undergoes a ring-chain tautomeric rearrangement to form a cyclic structure of 1,3-dihydro-1,3-dihydroxy-4-formylbenzo[c][2,1]oxaborole predominating in acetone-d6 solution and characterized by X-ray diffraction.
Two isomeric boronated ortho-phthalaldehydes 3- and 4-[B(OH)2]-1,2-C6H3(CHO)2 reveal a different structural behaviour in solution; the former compound undergoes a tautomeric rearrangement to form 1,3-dihydro-1,3-dihydroxy-4-formylbenzo[c][2,1]oxaborole.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 14, 15 June 2007, Pages 2924–2929
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 14, 15 June 2007, Pages 2924–2929
نویسندگان
Sergiusz Luliński, Janusz Serwatowski,