کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327339 | 977475 | 2009 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Dehydrogenation of N-ethyl perhydrocarbazole catalyzed by PCP pincer iridium complexes: Evaluation of a homogenous hydrogen storage system Dehydrogenation of N-ethyl perhydrocarbazole catalyzed by PCP pincer iridium complexes: Evaluation of a homogenous hydrogen storage system](/preview/png/1327339.png)
The iridium complexes IrH2{C6H3-2,6-(CH2PBut2)2 (1), IrH2{C6H3-2,6-(CH2PPri2)2 (2), and IrHCl{C6H3-2,6-(OPBut2)2 (3) have been found to be highly active catalysts for the dehydrogenation of N-ethyl perhydrocarbazole at 200 °C. However, dehydrogenation to the fully unsaturated ethyl carbazole does not occur in most instances. Complex 3 is the most active catalyst and shows reasonable activity even at 150 °C. No signs of dehydrogenation were found in experiments conducted at 100 °C. This apparently reflects the thermodynamic constraints imposed by the high enthalpy of dehydrogenation of the substrate.
The iridium complexes IrH2{C6H3-2,6-(CH2PBut2)2 (1), IrH2{C6H3-2,6-(CH2PPri2)2 (2), and IrHCl{C6H3-2,6-(OPBut2)2 (3) have been found to be highly active catalysts for the dehydrogenation of N-ethyl perhydrocarbazole at 200 °C. However, dehydrogenation to the fully unsaturated ethyl carbazole does not occur in most instances. Complex 3 is the most active catalyst and shows a reasonable activity at 150 °C.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 17, 1 August 2009, Pages 2854–2857