کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327388 | 977479 | 2005 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Diels–Alder reaction of anthracene on carbosilane dendrimer Diels–Alder reaction of anthracene on carbosilane dendrimer](/preview/png/1327388.png)
The dendritic macromolecule with 4, 8, 16 and 32 bicyclo end groups on the periphery has been created by the Diels–Alder reaction of anthracene and maleimide. The dendritic skeleton with triple bonds has been prepared by the hydrosilation and the alkynylation of bis(phenylethynyl)dimethylsilane as a core. The peripheral anthracene on dendrimers has been substituted by the reaction of chlorosilyl groups containing dendritic generations and 9-anthracenecarbinol. NMR and MALDI-TOF mass spectrum has characterized these Diels–Alder products.
The dendritic macromolecule with 4, 8, 16 and 32 bicyclo end groups on the periphery has been created by the Diels-Alder reaction of anthracene and maleimide. NMR and MALDI-TOF mass spectrum has characterized these products.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 690, Issue 13, 1 July 2005, Pages 3278–3285