کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327413 | 977480 | 2009 | 6 صفحه PDF | دانلود رایگان |

Reactions of 2,6-bis(bromomethyl)pyridine with 3,5-dimethylpyrazole and 1H-indazole yield the terdentate ligands 2,6-bis(3,5-dimethylpyrazol-1-ylmethyl)pyridine (5) and 2,6-bis(indazol-2-ylmethyl)pyridine (6). The molecular structure of the new compound 6 was determined by single-crystal X-ray diffraction. These ligands react with the CrCl3(THF)3 complex in THF to form neutral complexes of general formula [CrCl3{2,6-bis(azolylmethyl)pyridine-N,N,N}] (7, 8) which are isolated in high yields as stable green solids and characterized by means of elemental analysis, magnetic moments, IR, and mass spectroscopy. Theoretical calculations predict that the thermodynamically preferred structure of the complexes is the fac configuration. After reaction with methylaluminoxane (MAO) the chromium(III) complexes are active in the polymerization of ethylene.
2,6-Bis(azolylmethyl)pyridine ligands are obtained by reaction of 2,6-bis(bromomethyl)pyridine with 3,5-dimethylpyrazole and 1H-indazole. The molecular structure of the ligand 2,6-bis(indazol-2-ylmethyl)pyridine was determined by single-crystal X-ray diffraction. These ligands react with the CrCl3(THF)3 complex to form octahedral complexes formula [CrCl3{2,6-bis(azolylmethyl)pyridine-N,N,N}]. Theoretical calculations show that the thermodynamically preferred structure of the complexes is the fac configuration. After reaction with methylaluminoxane (MAO) the chromium(III) complexes are active in the polymerization of ethylene.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 16, 15 July 2009, Pages 2636–2641