کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1327495 | 977485 | 2009 | 7 صفحه PDF | دانلود رایگان |
New molecular conductors on the base of 8,8′-diiodo cobalt bis(dicarbollide) anion (TTF)[8,8′-I2-3,3′-Co(1,2-C2B9H10)2] (1), (BMDT-TTF)4[8,8′-I2-3,3′-Co(1,2-C2B9H10)2] (2) and (BEDT-TTF)2[8,8′-I2-3,3′-Co(1,2-C2B9H10)2] (3) were synthesized and their crystal structures and electrical conductivities were determined. All the radical cation salts prepared were found to be semiconductors. Some regularities in the crystal structures of the TTF-based radical cation salts with bis(dicarbollide) complexes of transition metals are discussed.
New molecular conductors (TTF)[8,8′-I2-3,3′-Co(1,2-C2B9H10)2] (1), (BMDT-TTF)4[8,8′-I2-3,3′-Co(1,2-C2B9H10)2] (2) and (BEDT-TTF)2[8,8′-I2-3,3′-Co(1,2-C2B9H10)2] (3) were synthesized and their crystal structures and electrical conductivities were determined. Some regularities in the crystal structures of the TTF-based radical cation salts with bis(dicarbollide) complexes of transition metals are discussed.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 15, 1 July 2009, Pages 2336–2342