کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327663 | 977496 | 2006 | 4 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Polymeric assembling through reciprocal metal-η2-arene π-interactions: Synthesis and X-ray characterization of [HgII(RPhNNNPhR′)2Py]2 (R = NO2, R′ = F), an asymmetric bis diaryl-substituted triazenide–pyridinyl complex of Hg(II) Polymeric assembling through reciprocal metal-η2-arene π-interactions: Synthesis and X-ray characterization of [HgII(RPhNNNPhR′)2Py]2 (R = NO2, R′ = F), an asymmetric bis diaryl-substituted triazenide–pyridinyl complex of Hg(II)](/preview/png/1327663.png)
Hg(SCN)2 reacts with 3-(2-fluorophenyl)-1-(4-nitrophenyl)triazene in tetrahydrofuran in the presence of triethylamine to give orange crystals of [HgII(RPhNNNPhR′)2Py]2 (R = NO2, R′ = F), a new polymeric triazenide–pyridinyl complex of Hg(II) with reciprocal metal-η2-arene π-interactions. The crystal structure belongs to the triclinic space group P1¯, and the lattice of [HgII(RPhNNNPhR′)2Py]2 can be viewed as a supramolecular unidimensional assembling of tectonic [HgII(RPhNNNPhR′)2Py] units linked through intermolecular metal-arene π interactions and non-classical C–H⋯O hydrogen bonding.
Hg(SCN)2 reacts with 3-(2-fluorophenyl)-1-(4-nitrophenyl)triazene in the presence of triethylamine and pyridine to give [HgII(RPhNNNPhR′)2Py]2 (R = NO2, R′ = F), a new triazenide–pyridinyl complex of Hg(II) with reciprocal metal-η2-arene π-interactions, whose lattice can be viewed as a supramolecular unidimensional assembling of [HgII(RPhNNNPhR′)2Py] tectonic units linked through intermolecular metal-arene π interactions and non-classical C–H⋯O hydrogen bonding.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 5, 15 February 2006, Pages 1051–1054