Ansa-vanadocene complexes with short interannular bridges

The new ansa-vanadocene complexes with short interannular bridges (CH3)2C(C5H4)2VX2 (X = Cl, Br) were prepared, characterized by spectroscopic methods and X-ray structural analysis. It was shown, that connection of cyclopentadienyl rings by dimethylmethane bridge affects the structural parameters. The behavior ansa-vanadocene dichloride in aqueous solution in presence of bio-ligands was studied by EPR spectroscopy.

The new ansa-vanadocene complexes with short interannular bridges (CH3)2C(C5H4)2VX2 (X = Cl, Br) were prepared, characterized by spectroscopic methods and X-ray structural analysis. The behavior ansa-vanadocene dichloride in aqueous solution in presence of bio-ligands was studied by EPR spectroscopy.Figure optionsDownload as PowerPoint slide