کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1327738 1499951 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Syntheses and structural characterization of novel heteroannular cyclopalladated ferrocenylimine
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Syntheses and structural characterization of novel heteroannular cyclopalladated ferrocenylimine
چکیده انگلیسی

A new heteroannular cyclopalladated ferrocene derivative [PdCl{C5H4FeC5H4CH2NCH–C4H3S}(PPh3)] (6) was synthesized and characterized by IR, 1H NMR, 13C NMR, high resolution mass spectroscopy, and its molecular structure was further confirmed by X-ray crystal structure determination. According to the crystal structure, the palladium atom is bound to the unsubstituted Cp ring, showing the four-coordinate structure typical of palladium complexes. A preliminary application of these novel cyclopalladated complexes in Mizoroki–Heck reaction is also to be demonstrated in this paper.

This paper describing the synthesis of cyclopalladated ferrocenylimines shows that the unsubstituted Cp ring was palladated, resulting in a novel heteroannular cyclopalladated ferrocenylimine. In addition, preliminary application of this novel cyclopalladated complex in Heck reaction was also demonstrated in this paper.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 691, Issues 1–2, 1 January 2006, Pages 255–260
نویسندگان
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