کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1327753 | 977502 | 2009 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Pincer-type bis(carbene)-derived complexes of nickel(II): Synthesis, structure, and catalytic activity
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
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چکیده انگلیسی
Air- and moisture-stable NHC (N-heterocyclic carbene)-derived CNC-type pincer complexes of nickel(II) 4a–d were successfully synthesized, and their structures were fully characterized using X-ray crystallography and analytical and spectroscopic methods. These complexes exhibit a high catalytic activity for the Suzuki–Miyaura coupling reaction of aryl bromides and chlorides with aryl- and alkenylboronic acids, providing an array of biphenyls and stilbenes generally in high yields.
A series of new CNC-type pincer complexes of nickel were successfully synthesized and fully characterized. The catalytic activity of these nickelacycles in the Suzuki–Miyaura coupling reaction also is described.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 3, 1 February 2009, Pages 389–396
Journal: Journal of Organometallic Chemistry - Volume 694, Issue 3, 1 February 2009, Pages 389–396
نویسندگان
Kiyofumi Inamoto, Jun-ichi Kuroda, Eunsang Kwon, Kou Hiroya, Takayuki Doi,