Synthesis, characterization, and polymerization activity of (pentamethylcyclopentadienyl)titanatranes containing {(O-2,4-Me2C6H2-6-CH2)nN(CH2CH2O)3−n}3− (n = 0–2) or {N(C6H4-2-O)3}3−

(Pentamethylcyclopentadienyl)titanatranes, Cp∗Ti{(O-2,4-Me2C6H2-6-CH2)nN(CH2CH2O)3−n} (n = 0, 1; n = 1, 2; n = 2, 3), featuring three five-membered chelating rings (1) to two six-membered chelating rings (3) in a stepwise fashion through 2 were synthesized from the corresponding tri-hydroxy chelating ligands 1L–3L, respectively, using Cp∗TiCl3 and triethylamine. Cp∗Ti{(O-2-C6H4)3N} (4) having three five-membered chelating rings from fully deprotonated N(C6H4-2-OH)3 (4L) was also synthesized. X-ray analysis shows that 2 and 4 have slightly distorted trigonal bipyramidal geometry around Ti. These compounds exhibited good catalytic activity for the syndiospecific polymerization of styrene in the presence of MAO at various polymerization conditions.

New (pentamethylcyclopentadienyl)titanatranes, Cp∗Ti{(O-2,4-Me2C6H2-6-CH2)nN(CH2CH2O)3−n} (n = 0–2) and Cp∗Ti{(O-2-C6H4)3N} were synthesized from Cp∗TiCl3 with the corresponding tri-hydroxy chelating ligands in the presence of NEt3. These compounds exhibited good catalytic activity for the syndiospecific polymerization of styrene at various polymerization conditions.Figure optionsDownload as PowerPoint slide