کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1327963 | 977520 | 2008 | 9 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Cyclopentadienyl chromium and tungsten complexes with halide, methyl and σ-phenylethynyl ligands: Structures of (η5-C5H5)Cr(NO)2(–CC–C6H5), (η5-C5H5)Cr(NO)2I and [(η5-C5H4)-COOCH3]W(CO)3Cl Cyclopentadienyl chromium and tungsten complexes with halide, methyl and σ-phenylethynyl ligands: Structures of (η5-C5H5)Cr(NO)2(–CC–C6H5), (η5-C5H5)Cr(NO)2I and [(η5-C5H4)-COOCH3]W(CO)3Cl](/preview/png/1327963.png)
With copper(I) iodide as catalyst, σ-alkynyls, compounds (η5-C5H5)Cr(NO)2(CC–C6H5) (5), [(η5-C5H4)-COOCH3]Cr(NO)2(CC–C6H5) (10), and [(η5-C5H4)-COOCH3]W(CO)3(CC–C6H5) (13), were prepared from their corresponding metal chloride 1, 6 and 12. Structures of compound 3, 5 and 12 have been solved by X-ray diffraction studies. In the case of 5, there is an internal mirror plane passing through the phenylethynyl ligand and bisecting the Cp ring. The phenyl group is oriented perpendicularly to the Cp with an eclipsed conformation. The twist angle is 0° and 118.4° for –CC–Ph and two NO ligands, respectively. The orientation is rationalized in terms of orbital overlap between ψ3 of Cp, dπ of Cr atom, and π∗ of alkynyl ligand, and complemented by molecular orbital calculation. The opposite correlation was observed on the chemical shift assignments of C(2)–C(5) on Cp ring in compounds 6 and 12, using HetCOR NMR spectroscopy. The electron density distribution in the cyclopentadienyl ring is discussed on the basis of 13C NMR data and compared with the calculations via density functional B3LYP correlation-exchange method.
With copper(I) iodide as catalyst, CpCr(NO)2(CC–C6H5) (5), [(η5-C5H4)-COOCH3]Cr(NO)2 (CC–C6H5) (10), and [(η5-C5H4)-COOCH3]W(CO)3(CC–C6H5) (13), were prepared. The phenyl group in 5 is oriented perpendicularly to the Cp with an eclipsed conformation. The orientation is rationalized and complemented by molecular orbital calculation. The opposite correlation was observed on the chemical shift assignments of C(2)–C(5) on Cp ring in compounds of [(η5-C5H4)-COOCH3]Cr(NO)2X and [(η5-C5H4)-COOCH3]W(CO)3X, using HetCOR NMR spectroscopy. The electron density distribution in the cyclopentadienyl ring is discussed on the basis of 13C NMR data and compared with the calculations via density functional B3LYP correlation-exchange method.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 693, Issue 15, 15 July 2008, Pages 2615–2623