کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1327986 1499948 2008 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, structures, and properties of iridium(III) bis-cyclometallated complexes containing three-atom chelates
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
Synthesis, structures, and properties of iridium(III) bis-cyclometallated complexes containing three-atom chelates
چکیده انگلیسی

Heating of [Ir(η2-ppy)2(MeCN)2]NO3 (1, ppy = 2-phenylpyridine) in MeCN under reflux afforded [Ir(η2-ppy)2(η2-NO3)] (2). Treatment of 1 with 2-mercaptopyridine (Hmp), 6-methyl-2-hydroxypyridine (Hmhp), 6-chloro-2-hydroxypyridine (Hchp), trimethylacetic acid (Htma), benzoic acid (Hbz), 2-methylacrylic acid (Hma), and acetic acid (Hac) in the presence of excess Et3N produced [Ir(η2-ppy)2(η2-XZY)] (XZY− = mp− (3), mhp− (4), chp− (5), ac− (6), bz− (7), ma− (8), tma− (9)). Crystal structures of 2, 3, 7, 8, and 9 have been characterized by X-ray diffraction. The inherent strain contained in the four-member rings, {Ir(η2-XZY)}, is apparently reflected in the long Ir–X and Ir–Y distances. The absorption and emission properties of nearly all the new complexes except 2 show small variations.

Eight bis-cyclometallated (C∧N) iridium(III) complexes containing three-atom chelates (XZY), [Ir(η2-ppy)2 (η2-XZY)] (XZY− = NO3−, deprotonated anions of 2-mercaptopyridine, 6-methyl-2-hydroxypyridine, 6-chloro-2-hydroxypyridine, acetic acid, benzoic acid, 2-methylacrylic acid, and 1,1,1-trimethylacetic acid) have been synthesized and fully characterized with some structures determined by X-ray diffraction. Both photoluminescence and electrochemical behavior of the green-emitting complexes are also studied.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 693, Issues 8–9, 15 April 2008, Pages 1510–1517
نویسندگان
, , , , , ,