Reactions of the titanium-carbide species CpTi(μ2-Me)(μ2-NPi-Pr3)(μ4-C)(AlMe2)3

The reaction of CpTi(μ2-Me)(μ2-NPi-Pr3)(μ4-C)(AlMe2)3 with ClSnMe3 and MeO3SCF3 affords the species CpTi(μ2-Cl)(μ2-NPi-Pr3)(μ4-C)(μ2-Cl)(AlMe)(AlMe2)21 and CpTi(μ2-Me)(μ2-NPi-Pr3)(μ4-C)(μ2-O3SCF3)(AlMe)(AlMe2)22, respectively. Both 1 and 2 have been structurally characterized.

TOC EntryReaction of CpTi(μ2-Me)(μ2-NPi-Pr3)(μ4-C)(AlMe2)3 with ClSnMe3 and MeO3SCF3 afford the species [CpTi(μ2-Cl)(μ2-NPi-Pr3)(μ4-C)(μ2-Cl)(AlMe)(AlMe2)2] 1 and [CpTi(μ2-Me)(μ2-NPi-Pr3)(μ4-C)(μ2-O3SCF3)(AlMe)(AlMe2)2] 2, respectively.Figure optionsDownload as PowerPoint slide