کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1328208 | 977549 | 2007 | 6 صفحه PDF | دانلود رایگان |
The binuclear half-sandwich iridium complexes {Cp∗IrCl2}2(μ-2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene) (3) and {Cp∗Ir[E2C2(B10H10)]}2(μ-2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene) (E = S(5a), Se(5b)) were prepared from the reaction of [Cp∗IrCl(μ-Cl)]2 or the “pseudo-aromatic” half-sandwich iridium complex Cp∗Ir[E2C2(B10H10)] (E = S(4a), Se(4b)) with a tetrathiafulvalene (TTF) derivative 2,6-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene (2) at room temperature. The complexes (3, 5a and 5b) have been fully characterized by IR and NMR spectroscopy, as well as elemental analysis. And the molecular structures of 2 and 5a were established through X-ray crystallography. It is interesting that infinite tunnels are created by repeating ‘buckled bowl’ molecules of 5a.
Binuclear half-sandwich dichalcogenolate carborane iridium complexes 5a and 5b, connected with 2,6(7)-bis(4-pyridyl)-1,4,5,8-tetrathiafulvalene ligands, have been synthesized and characterized structurally.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 21, 1 October 2007, Pages 4545–4550