کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328213 | 977549 | 2007 | 10 صفحه PDF | دانلود رایگان |
Novel carbohydrate bearing imidazolium salts have been synthesized and used for the in situ generation of the corresponding N-heterocyclic carbenes. These compounds were successfully used as catalysts of the conjugate umpolung of cinnamaldehyde to form γ-butyrolactones. In addition, silver and palladium complexes of these N-heterocyclic carbenes were synthesized and structurally characterized.
Novel carbohydrate bearing imidazolium salts have been synthesized and used for the in situ generation of the corresponding N-heterocyclic carbenes 1. These compounds were successfully used as catalysts of the conjugate umpolung of cinnamaldehyde to form γ-butyrolactones. In addition, silver and palladium complexes of these N-heterocyclic carbenes were synthesized and structurally characterized.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 21, 1 October 2007, Pages 4593–4602