New o-methoxyphenylcyclopentadienylchromium (III) complexes: Synthesis, structures and catalytic properties for ethylene polymerization

Two new ligands 1-(2-methoxyphenyl)-3,4-diphenylcyclopentadiene (1) and 1-(2-methoxyphenyl)-2,3,4,5-tetramethylcyclopentadiene (2), as well as their corresponding cyclopentadienylchromium complexes η5-1-(2-methoxyphenyl)-3,4-diphenylcyclopentadienyl chromium dichloride (3) and η5-1-(2-methoxyphenyl)-2,3,4,5-tetramethylcyclopentadienyl chromium dichloride (4) were synthesized and characterized. Molecular structures of 3 and 4 were determined by single-crystal X-ray diffraction. Complexes 3 and 4 were tested as catalyst precursors for ethylene polymerization. When activated with Al(iBu)3 and Ph3C+B(C6F5)4-, complex 3 shows reasonable catalytic activity while 4 exhibits high catalytic activity for ethylene polymerization. The effects of temperature and Al/Cr ratio on the catalytic activity were studied. The molecular weight and melting temperature of the produced polyethylenes were determined.

Two new chromium complexes η5-1-(2-methoxyphenyl)-3,4-diphenylcyclopentadienyl chromium dichloride and η5-1-(2-methoxyphenyl)-2,3,4,5-tetramethylcyclopentadienyl chromium dichloride were synthesized and characterized. Both complexes exhibited high catalytic activities for ethylene polymerization in the presence of Al(iBu)3 and Ph3C+B(C6F5)4-.Figure optionsDownload as PowerPoint slide