کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328280 | 977559 | 2007 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A novel application of tin-based alkoxide anion for deacetylation
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی معدنی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: A novel application of tin-based alkoxide anion for deacetylation A novel application of tin-based alkoxide anion for deacetylation](/preview/png/1328280.png)
چکیده انگلیسی
A stannylene acetal, in the presence of CsF, is able to cleave both aromatic and aliphatic acetates rapidly and efficiently under room temperature. Control experiments indicate that both the stannylene acetal and CsF are required and play significant roles in the deacetylation process. Thus, it is likely that the tin-based alkoxide anion generated by a stannylene acetal and CsF is responsible for deacetylation.
A combination of cyclic dialkyltin alkoxide with CsF can deacetylate acetates under very mild condition, and a likely deacetylation mechanism is proposed.Figure optionsDownload as PowerPoint slide
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 7, 1 March 2007, Pages 1619–1622
Journal: Journal of Organometallic Chemistry - Volume 692, Issue 7, 1 March 2007, Pages 1619–1622
نویسندگان
Weiying Lin, Lingliang long, Daiwei Peng, Cancheng Guo,