کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1328316 | 1499949 | 2007 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: Reactions of trisilaallene and 2-germadisilaallene with various reagents Reactions of trisilaallene and 2-germadisilaallene with various reagents](/preview/png/1328316.png)
A number of the distinctive reactions of trisilaallene 1 and 2-germadisilaallene 4 with various reagents including water, alcohols, acetone, and haloalkanes were studied. The addition reactions of 1 to water and alcohols occur in a regiospecific manner to afford 1,3-dioxytrisilanes in high yields. The additions are explained by a stepwise mechanism involving the initial nucleophilic attack of a hydroxy oxygen to a terminal allenic silicon to give an intermediate unsymmetric disilene. The regiospecificity is rationalized by the shape of the frontier molecular orbitals and the NPA charge distribution of trisilaallene 1 and the intermediate disilene.
Heavier group-14 element congeners of allene, a trisilaallene and a 2-germadisilaallene, react with water and alcohols to afford the corresponding 1:2 addition products in high yields in an regiospecific manner. The regiospecificity is rationalized by the unique electronic characteristics of heavier group-14 allenes revealed by theoretical calculations.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 692, Issues 1–3, 1 January 2007, Pages 263–270