کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
1328415 | 977569 | 2006 | 14 صفحه PDF | دانلود رایگان |

A series of triorganotin (IV) complexes with 2,3,4,5-tetrafluorobenzoic acid and mixed-ligands of the types: R3Sn(O2CC6HF4)m · L (m = 1, L = 0, R = Ph 1; m = 1, L = Ph3PO, R = Ph 4, Me 5), [R3Sn(O2CC6HF4)]m · L (m = 2, L = 4,4′-bipy, R = Ph 2, Me 3; m = n, L = 0, R = Me 6), and [R3Sn(O2CC6HF4) · (H2O)]m · L · C2H5OH (m = 2, L = Phen, R = Ph 7, Me 8), (4,4′-bipy = 4,4′-bipyridyl; Phen = 1,10-phenanthroline), have been synthesized by the reaction of triorganotin chloride and 2,3,4,5-tetrafluorobenzoic acid in the presence of mixed-ligands: 4,4′-bipy, triphenylphosphine oxide, or phen. All complexes were characterized by elemental analysis, IR, 1H, 13C, 119Sn NMR spectroscopy analysis. Except for 5 and 8, all the complexes were also characterized by X-ray crystallography.
A series of triorganotin(IV) complexes with 2,3,4,5-tetrafluorobenzoic acid and mixed-ligands of the types: R3Sn(O2CC6HF4)m · L (m = 1, L = 0, R = Ph 1; m = 1, L = Ph3PO, R = Ph 4, Me 5), [R3Sn(O2CC6HF4)]m · L (m = 2, L = 4,4′-bipy, R = Ph 2, Me 3; m = n, L = 0, R = Me 6), and [R3Sn(O2CC6HF4) · (H2O)]m · L · C2H5OH (m = 2, L = Phen, R = Ph 7, Me 8), (4,4′-bipy = 4,4′-bipyridyl; Phen = 1,10-phenanthroline), have been synthesized by the reaction of triorganotin chloride and 2,3,4,5-tetrafluorobenzoic acid in the presence of mixed-ligands: 4,4′-bipy, triphenylphosphine oxide, or phen. All complexes were characterized by elemental analysis, IR, 1H, 13C, 119Sn NMR spectroscopy analysis. Except for 5 and 8, all the complexes were also characterized by X-ray crystallography.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 26, 15 December 2006, Pages 5873–5886