کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
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1328423 | 977569 | 2006 | 9 صفحه PDF | دانلود رایگان |

Rigid spacer-chelator with the framework of 3 has been prepared. Building units with two parallel coordination sites such as salen and oxazoline units have also been synthesized. The spacer-chelators, 11 and 15, readily self-assembled with metal complexes such as Zn++ and Co++ to form molecular rectangles. The overall dimensions of the rectangles, 13 and 17, are 6.2 Å × 23.5 Å. The characterization of the supramolecules by NMR, mass spectroscopy, and X-ray crystal structures is also reported.
Building units with two parallel coordination sites such as salen and oxazoline units have been synthesized. The spacer-chelators readily self-assembled with metal acetates such as Zn++ and Co++ to form molecular rectangles. The overall dimensions of the rectangles are 6.2 Å × 23.5 Å.Figure optionsDownload as PowerPoint slide
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 26, 15 December 2006, Pages 5946–5954