کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
1328439 977574 2006 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
A new synthesis for thermolabile low-valent palladium complexes by electron transfer reactions from nickel(0) to palladium(II) compounds
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی معدنی
پیش نمایش صفحه اول مقاله
A new synthesis for thermolabile low-valent palladium complexes by electron transfer reactions from nickel(0) to palladium(II) compounds
چکیده انگلیسی

The nickel(0) complex [Ni(bpy)(cod)] (bpy: 2,2′-bipyridine, cod: cycloocta-1,5-diene) was used as a mild reducing reagent for the synthesis of the extremely reactive low-valent palladium complexes [Pd2X2(cod)2] (1: X = Cl, 2: X = Br), Pd(cod)2 (3) and Pd(norbornene)3 (4). The X-ray analysis of 1 showed that the two [Pd(cod)(Cl)] moieties are only connected by a short Pd(I)–Pd(I) bond (bond length: 2.5379(4) Å) with the chloride ions as monodentate ligands. The X-ray structure of 3 which is also known to be an extremely reactive compound could be determined by X-ray diffraction. As expected, the Pd(0) centre is surrounded by the two cod ligands to form a PdC4 tetrahedron with typical Pd–C bond lengths. The crystal structure of 3 shows it to be very similar to the closely related complexes M(cod)2 (M: Ni, Pt). The X-ray structure of 4 displays that the Pd(0) centre is in a trigonal planar environment of the three olefin groups. According to 1H NMR measurements the complexes have the same structure in solution as found in the solid state.

The nickel(0) complex [Ni(bpy)(cod)] (bpy: 2.2′-bipyridine, cod: cycloocta-1.5-diene) was used as a mild reducing reagent for the synthesis of the extremely reactive low-valent palladium complexes [Pd2X2(cod)2] (1: X = Cl, 2: X = Br), Pd(cod)2 (3) and Pd(norbornene)3 (4). Compounds 1–4 were structurally characterized by 1H NMR spectroscopy and X-ray analyses.Figure optionsDownload as PowerPoint slide

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Organometallic Chemistry - Volume 691, Issue 23, 15 November 2006, Pages 4868–4873
نویسندگان
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